Solar
Cloths – Postdoctoral Positions Available “Solar
cloth” is a non-woven fiber cloth that could be produced by
electrospinning a
polymeric hole-conducting solution in which dye-anchored wide bandgap
semiconductors are dispersed. This concept is schematically shown
below.
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Figure
shows the concept of photovoltaic fibers. The PV fibers are visualized
as a non-woven fiber cloth (A).
The fiber is a percolating network of one-dimensional nanostructures
such as nanowires dispersed in a
polymeric hole conducting medium (B). Organic flourophores such as
dyes or semiconducting quantum dots
could be anchored to the nanowires widen the absorption wavelength
window (C). Light absorption by the
flourophores leads to excitation of electrons to unoccupied molecular
orbitals which are then injected to the
conduction band of the wide bandgap metal oxide semiconductor; the
oxidized flourophores are regenerated
by a hole-conductor
Efficiency of photovoltaic conversion depends (i)
on the degree to which the two species,
i.e., dye-anchored semiconductor and the polymeric hole-conductor,
form a percolating
network, (ii) efficiency of charge transport, (iii) and efficiency
of charge collection. |